Dr. Emanuel Hupf
Universität Bremen
Fachbereich 2: Biologie/Chemie
Institut für Anorganische Chemie und Kristallographie
Universitätslektor
Leobener Straße 7 — Gebäude NW2 - Raum C2020
28359 Bremen
Büro Tel.: +49 (0)421 218-63161
Publikationen
| 60 | P. Komorr, C. Stoian, A. Radovic , B. A. Meyer, P. Puylaert, G. E. Cutsail III, E. Hupf, J. Beckmann Isolation of kinetically-stabilised diarylchalcogenide radical cations. Commun. Chem. 2025, 8, 239 | www |
| 59 | O. Moždiak, T. Bíza, L. Střižík, Z. Růžičková, M. Erben, L. Dostál, E. Hupf, R. Jambor From Hydroborations Catalyzed by Sn(II) Cations to Photoluminescent Boronic Esters. Chem. Cat. Chem. 2025, 17, e00462 | www |
| 58 | F. Meyer, A. Siumbeli, L. Dostál, E. Hupf, J. Beckmann Nature of the heavy formal double bonds As=Ch, Sb=Ch and Bi=Ch (Ch = S, Se, Te) in NCN-pincer supported arsinidene, stibinidene and bismuthinidene chalcogenides. Chem. Sci. 2025, 16, pp. 16232–16239 | www |
| 57 | M. Hejda, L. Doležal, M. Erben, E. Hupf, A. Ružicka, J. Beckmann, L. Dostál Redox Cycling at Tellurium: Selective and Multiple Activation of Si-H Bonds in Common Organosilanes and SiH4. Chem. Eur. J. 2025, 31, e202502141 | www |
| 56 | C. Stoian, N. Schmidt, T.J. Kuczmera, P. Puylaert, E. Lork, B. J. Nachtsheim, E. Hupf, J. Beckmann Oxidative addition of diaryldichalcogenides to the diferrocenylphosphenium ion: synthesis, structure and organocatalytic activity. Chem. Comm. 2025, 61, pp. 8256–8259 | www |
| 55 | M. Heitmann, D. Duvinage, C. Golz, E. Hupf, J. Beckmann, M. Fischer Structural Snapshots on Stepwise Anionic Oxoborane Formation: Access to an Acyclic BO Ketone Analogue and Its Metathesis Chemistry with CO2 and CS2. Inorg. Chem. 2025, 64, pp. 3028–3037 | www |
| 54 | M. Hejda, L. Doležal, M. Erben, E. Hupf, A. Ružicka, J. Beckmann, L. Dostál Redox Cycling at Tellurium: Selective and Multiple Activation of Si-H Bonds in Common Organosilanes and SiH4. Chem. Eur. J. 2025, 31, e202502141 | www |
| 53 | M. Molkenthin, E. Hupf, B. J. Nachtsheim Dibenzyl isophthalates as versatile hosts in room temperature phosphorescence host–guest systems. Chem. Sci. 2025, 16, 2819 - 2829 | www |
| 52 | C. Stoian, M. Olaru, S. Demeshko, M. Fischer, S. Mebs, E. Hupf J. Beckmann Heavier Diferrocenylpnictogenium Ions. Chem. Eur. J. 2025, 31, e202403555 | www |
| 51 | I. Heuermann, F. Mostaghimi, E. Lork, S. Mebs, E. Hupf J. Beckmann Probing Donor Acceptor Interactions of Chalcogenide Supported Fluorophosphonium Ions Using peri-substituted Acenaphthyl Scaffolds. Eur. J. Inorg. Chem. 2024, 27, e202400536 | www |
| 50 | F. Meyer, E. Lork, E. Hupf J. Beckmann Synthesis and Reactivity of Bis[2,6-Bis(Diphenylphosphino) Phenyl]Antimony Chloride Towards Mercury Chlorides Unexpected. Transmetallation and Sb-Sb Bond Formation. Z. Anorg. Allg. Chem. 2024, 650, e202400172 | www |
| 49 | D. Duvinage, L.A Malaspina, S. Mebs, S. Grabowsky, E. Hupf J. Beckmann Hirshfeld Atom Refinement (HAR) and Complementary Bonding Analysis of Lithium m-Terphenylhydridoborates Containing B-H···Li Linkages. Chem. Eur. J. 2024, 30, e202403218 | www |
| 48 | F. Meyer, P. Puylaert, D. Duvinage, E. Hupf, J. Beckmann Cationic dinuclear complexes [M2(PCP)2µ-Cl][GaCl4] of the group 10 elements. Metallophilic interactions and catalytic dehydrogenation of Me2NHBH3. ChemComm 2024, 88, 12912-12915. | www |
| 47 | C. Stoian, F. Al Hussein, W.R. Browne, E. Hupf, J. Beckmann Electronic Coupling in Triferrocenylpnictogens. ACS Organic & Inorganic Au 2024, 5, 545-556. | www |
| 46 | M. Janssen, T. Friederichs, M. OLaru, E. Lork, E. Hupf, J. Beckmann Synthesis of a stable crystalline nitrene. Science 2024, 385, 318-321. | www |
| 45 | M. Hejda, L. Doležal, Jan, Blahut, E. Hupf, J. Tydlitát, R. Jambor, A. Ružicka, J. Beckmann, L. Dostál N-Coordinated tellurenium(ii) and telluronium(iv) cations: synthesis, structure and hydrolysis. Dalton. Trans. 2024, 52, 16235-16248. | www |
| 44 | E.A. Chulanova, E.A Radiush, N.A. Semenov, E. Hupf, I.G Irtegova, Y.S Kosenkova, I.Y.Bagryanskaya, L.A Shundrin, J. Beckmann, A.V. Zibarev Tuning Molecular Electron Affinities against Atomic Electronegativities by Spatial Expansion of a p-System. Chem.Phys.Chem. 2023 52, 5918-5925 | www |
| 43 | F. Feige, L.A. Malaspina, F. Kleemiss, J.F. Kögel, S. Ketkov, E. Hupf,S. Grabowsky, J. Beckmann An investigation into the Brønsted acidity of the perfluorinated alkoxy silanes {(F3C)3CO}3SiH and {(F6C5)3CO}2Si(Cl)H. Dalton Trans. 2023 52, 5918-5925 | www |
| 42 | P. Komorr, M. Olaru, E. Hupf, S. Mebs, J. Beckmann Donor Acceptor Complexes between the Chalcogen Fluorides SF2, SeF2, SeF4 and TeF4 and an N-Heterocyclic Carbene. Chem. Eur. J. 2022, 28, Article number e202201023. | www |
| 40 | D. Duvinage, P. Puylaert, E.K. Wieduwilt, A.L. Malaspina, A. J. Edwards, E. Lork, S. Mebs, E. Hupf, S. Graboswky, J. Beckmann Nickel and Palladium Complexes of a PP(O)P Pincer Ligand Based upon a peri-Substituted Acenaphthyl Scaffold and a Secondary Phosphine Oxide. Inorg. Chem. 2022, 61, 8406-8418. | www |
| 40 | S. Furan, M. Molkenthin, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann Tris(6-diphenylphosphinoacenaphth-5-yl)gallium: Z-Type Ligand and Transmetalation Reagent. Organometallics 2021, 40, 3785-3796. | www |
| 39 | F. Feige, L.A. Malaspina, E. Rychagova, S. Ketkov, S. Grabowsky, E. Hupf, J. Beckmann Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity. J. Organomet. Chem. 2021, 27, 15898-15902. | www |
| 38 | S. Holsten, A.L. Malaspina, F. Kleemiss, S. Mebs, E. Hupf, S. Grabowsky, Beckmann Different Reactivities of (5-Ph2P-Ace-6-)2MeSiH toward the Rhodium(I) Chlorides [(C2H4)2RhCl]2and [(CO)2RhCl]2. Hirshfeld Atom Refinement of a Rh-H···Si Interaction. Organometallics 2021, 40, 2027-2038. | www |
| 37 | S. Furan, M. Vogt, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann (6-Diphenylphosphinoacenaphth-5-yl)indium and -nickel Compounds: Synthesis, structure, transmetalation, and cross-coupling reactions. Z. Anorg. Allg. Chem. 2021, 40, 1284-1295. | www |
| 36 | S. Furan, E. Hupf, E. Lork, J. Beckmann Synthesis and Structure of 5-Diphenylphosphino- acenaphth-6-yl Boronic Acid, Related Dialkyl Esters and Boroxine Rings. Z. Anorg. Allg. Chem . 2021, 647, 507-512. | www |
| 35 | F. Meyer, E. Hupf, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann Bis(6-diphenylphosphino-acenaphth-5-yl)sulfoxide: A New Ligand for Late Transition Metal Complexes. Eur. J. Inorg. Chem.2020, 2020, 3829–3836 . | www |
| 34 | S. Furan, E. Lork, S. Mebs, E. Hupf, J. Beckmann Transmetallation of Bis(6-diphenylphosphinoacenaphth-5-yl)-Mercury and -Tributyltin with Precious Metal Chlorides. Z. anorg. allg. Chem.2020, 646, 856–865 . | www |
| 33 | S. Furan, E. Hupf, E. Lork, J. Beckmann Synthesis and structure of 6-diphenylphosphinoacenaphth-5-yl bismuth compounds. Revue Roumaine de Chimie2020, 65, 673–676 . | www |
| 32 | R.S. Markl, N. Hohn, E. Hupf, L. Bießmann, V. Korstgens, L.P. Kreuzer, G. Mangiapia, M. Pomm, A. Kriele, E. Rivard, P. Muller-Buschbaum Comparing the backfilling of mesoporous titania thin films with hole conductors of different sizes sharing the same mass density. IUCrJ2020, 7, 268–275 . | www |
| 31 | S. Holsten, E. Hupf, E. Lork, S. Mebs, J. Beckmann Proximity enforced oxidative addition of a strong unpolar σ-Si-Si bond at rhodium(i). Dalt. Trans.2020, 49, 1731–1735 . | www |
| 30 | E. Hupf, F. Kaiser, P.A. Lummis, M.M.D. Roy, R. McDonald, M.J. Ferguson, F.E. Kühn, E. Rivard Linking Low-Coordinate Ge(II) Centers via Bridging Anionic N-Heterocyclic Olefin Ligands. Inorg. Chem.2020, 59, 1592–1601 . | www |
| 29 | F. Kleemiss, E.K. Wieduwilt, E. Hupf, M.W. Shi, S.G. Stewart, D. Jayatilaka, M. J. Turner, K, Sugimoto, E. Nishibori, T. Schirmesiter, T.C. Schmidt, B. Engels, S. Grabowsky Similarities and Differences between Crystal and Enzyme Environmental Effects on the Electron Density of Drug Molecules. Chem. Eur. J.2020, im Druck, . | www |
| 28 | E. Hupf, L.A. Malaspina, S. Holsten, F. Kleemiss, J. Beckmann, A.J. Edwards; J.R. Price, V. Kozich, K. Heyne, S. Mebs, S. Grabowsky, J. Beckmann Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions. Inorg. Chem.2019, 58, 16372–16378. | www |
| 27 | L.A. Malaspina, E.K. Wieduwilt, J. Bergmann, F. Kleemiss, B. Meyer, M.F. Ruiz-López, R. Pal, E. Hupf, J. Beckmann, R.O Piltz, A.J. Edwards, S. Grabowsky, A. Genoni Fast and Accurate Quantum Crystallography: From Small to Large, from Light to Heavy. J. Phys. Chem. Lett.2019, 10, 6973–6982. | www |
| 26 | S.M. Parke, S. Tanaka, H. Yu, E. Hupf, M.J. Ferguson,Y. Zhou, K. Naka, E. Rivard Highly Fluorescent Benzophosphole Oxide Block-Copolymer Micelles. Macromolecules2019, 52, 7477–7488. | www |
| 25 | E. Hupf, Y. Tsuchiya, W. Moffat, L. Xu, M. Hirai, Y. Zhou, M.J. Ferguson, R. McDonald, T. Murai, G. He, E. Rivard A Modular Approach to Phosphorescent π-Extended Heteroacenes. Inorg. Chem.2019, 58, 13323–13336. | www |
| 24 | K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C.A. Braun, W. Torres Delgado, L. Xu, E. Rivard, N. Iwasawa Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence. Chem. Eur. J.2019, 25, 8479–8483. | www |
| 23 | T.G. Do, E. Hupf, E. Lork, J.F. Kögel, F. Mohr, A. Brown, R. Toyoda, R. Sakamoto, H. Nishihara, S. Mebs, J. Beckmann Aurophilicity and Photoluminescence of (6-Diphenylpnicogenoacenaphth-5-yl)gold Compounds. Eur. J. Inorg. Chem.2019, 2019, 647–659. | www |
| 22 | T.G. Do, E. Hupf, E. Lork, S. Mebs, J. Beckmann Bis(6-diphenylphosphinoacenaphth-5-yl)telluride as a ligand toward coinage metal chlorides. Dalt. Trans.2019, 48, 2635–2645. | www |
| 21 | S. Furan, E. Hupf, J. Boidol, J. Brünig, E. Lork, S. Mebs, J. Beckmann Transition metal complexes of antimony centered ligands based upon acenaphthyl scaffolds. Coordination non-innocent or not?. Dalt. Trans.2019, 48, 4504–4513. | www |
| 20 | S.M. Parke, E. Hupf, G.K. Matharu, I. de Aguiar, L. Xu, H. Yu, M.P. Boone, G.L.C. de Souza, R. McDonald, M.J. Ferguson, H. He, A. Brown, E. Rivard Aerobic Solid State Red Phosphorescence from Benzobismole Monomers and Patternable Self-Assembled Block Copolymers. Angew. Chem. Int. Ed.2018, 57, 14841-14846. | www |
| 19 | T.G. Do, E. Hupf, E. Lork, J. Beckmann Bis(6-diphenylphosphinoacenaphth-5-yl)telluride as a ligand toward manganese and rhenium carbonyls. Molecules2018, 23, 2805. | www |
| 18 | S.M. Parke, M.A.B. Narreto, E. Hupf, R. McDonald, M.J. Ferguson, F.A. Hegmann, E. Rivard Understanding the origin of phosphorescence in bismoles: A synthetic and computational study. Inorg. Chem. 2018, 57,7536–7549. | www |
| 17 | M. Olaru, R. Kather, E. Hupf, S. Mebs, J. Beckmann A Monoaryllead Trichloride That Resists Reductive Elimination. Angew. Chem. Int. Ed.2018, 57,5917–5920. | www |
| 16 | M. Fugel, D. Jayatilaka, E. Hupf, J. Overgaard, V.R. Hathwar, P. Macchi, M.J Turneer, J.A.K. Howard, O.V. Dolomanov, H. Puschmann, B.B. Iversen, H.-B. Bürgi, S. Grabowsky Probing the accuracy and precision of Hirshfeld atom refinement with HARt interfaced with Olex2. IUCrJ2018, 5,32-44. | www |
| 15 | E. Hupf, M. Olaru, C.I. Raţ, M. Fugel, C.B Hübschle, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann Mapping the Trajectory of Nucleophilic Substitution at Silicon Using a peri-Substituted Acenaphthyl Scaffold. Chem. Eur. J.2017, 23,10568–10579. | www |
| 14 | S. Furan, E. Hupf, E. Lork, S. Mebs, J. Beckmann Insights into Frustrated and Regular peri-Substituted (Ace-)Naphthylaminoboranes and (Ace-)Naphthylphosphinoboranes. Eur. J. Inorg. Chem.2017, 2017,3302–3311. | www |
| 13 | E. Hupf, T.G. Do, A. Nordheider, M. Wehrhahn, P. Sanz Camacho, S.E. Ashbrook, E. Lork, A.M.Z. Slwain, S. Mebs, J.D. Woolins, J. Beckmann Selective Oxidation and Functionalization of 6-Diphenylphosphinoacenaphthyl-5-tellurenyl Species 6-Ph2P-Ace-5-TeX (X = Mes, Cl, O3SCF3). Various Types of P-E···Te(II,IV) Bonding Situations (E = O, S, Se). Organometallics2017, 36,1566-1579. | www |
| 12 | E. Hupf, R. Kather, M. Vogt, E. Lork, S. Mebs, J. Beckmann Role of Dispersion in Metallophilic Hg...M Interactions (M = Cu, Ag, Au) within Coinage Metal Complexes of Bis(6-diphenylphosphinoacenaphth-5-yl)mercury. Inorg. Chem.2016, 55,11513–11521. | www |
| 11 | T.G. Do, E. Hupf, A. Nordheider, E. Lork, A.M.Z. Slwain, S.G. Makarov, S.Y. Ketkov, S. Mebs, J.D. Woolins, J. Beckmann Intramolecularly Group 15 Stabilized Aryltellurenyl Halides and Triflates. Organometallics2015, 34,5341–5360. | www |
| 10 | E. Hupf, E. Lork, S. Mebs, J. Beckmann Sterically Congested 5-Diphenylphosphinoacenaphth-6-yl-silanes and -silanols. Organometallics2015, 34,3873–3887. | www |
| 9 | J. Brünig, E. Hupf,E. Lork, S. Mebs, J. Beckmann A tetranuclear arylstibonic acid with an adamantane type structure. Dalton. Trans.2015, 44,7105–7108. | www |
| 8 | A. Nordheider, E. Hupf, B.A. Chalmers, F.R Knight, M. Bühl, S. Mebs, L. Checińska, E. Lork, P.S. Camacho, S.E. Ashbrook, K.S. Athukorala Arachchige, D.B. Cordes, A.M.Z. Slawin, J. Beckmann, J.D. Woolins Peri -substituted phosphorus-tellurium systems-an experimental and theoretical investigation of the p⋯te through-space interaction. Inorg. Chem.2015, 54,2435–2446. | www |
| 7 | E. Hupf, E. Lork, S. Mebs, J. Beckmann 6-Diphenylphosphinoacenaphth-5-yl-mercurials as Ligands for d10 Metals. Observation of Closed-Shell Interactions of the Type Hg(II)⋯M; M = Hg(II), Ag(I), Au(I). Inorg. Chem.2015, 54,1847–1859. | www |
| 6 | E. Hupf, E. Lork, S. Mebs, L. Chęcińska, J. Beckmann Probing donor-acceptor interactions in peri -substituted diphenylphosphinoacenaphthyl-element dichlorides of group 13 and 15 elements. Organometallics2014, 33,7247-7259. | www |
| 5 | E. Hupf, E. Lork, S. Mebs, J. Beckmann Intramolecularly coordinated (6-(Diphenylphosphino)acenaphth-5-yl) stannanes. Repulsion vs attraction of P- and Sn-containing substituents in the peri positions. Organometallics2013, 33,2409-2423 | www |
| 4 | J. Beckmann, E. Hupf, E. Lork, S. Mebs Peri -substituted (Ace)naphthylphosphinoboranes. (Frustrated) Lewis Pairs. Inorg. Chem.2013, 52,11881-11888 | www |
| 3 | J. Beckmann, T.G. Do, S. Grabowsky, E. Hupf, E. Lork, S. Mebs Peri-interactions in 8-Diphenylphosphino-1-bromonaphthalene, 6-Diphenylphosphino-5-bromoacenaphthene, and derivatives. Z. anorg. allg. Chem.2013, 639,2233-2249 | www |
| 2 | J. Beckmann, E. Hupf, E. Lork Synthesis of 7,7,14,14-tetrachlorodinaphtho[1,8 bc :1′,8′-fg] [1,5]distannocine. Molecular structure of the di-water tetra-THF adduct. Main Group Met. Chem.2013, 36,145-149 | www |
| 1 | T. Bredtmann, E. Hupf, B. Paulus Electronic fluxes during large amplitude vibrations of single, double and triple bonds. Phys. Chem. Chem. Phys.2012, 14,15494-15501 | www |