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Publications

List of Publications

63A. H. Abazid, B. J. Nachtsheim "Application of chiral triazole-substituted iodoarenes in the enantioselective construction of spirooxazolines" Chem. Commun. 2021, 57, 8822-8825. DOI: https://doi.org/10.1039/D1CC03246A
62A. Boelke, S. Sadat, E. Lork, B. J. Nachtsheim "Pseudocyclic Bis-N-Heterocycle-stabilized Iodanes – Synthesis, Characterization and Applications" Chem. Commun.  2021 DOI: /10.1039/D1CC03097C, also published: ChemRxvi  2021 Preprint : https://doi.org/10.26434/chemrxiv.14754525.v1
61

A. Boelke, T. Kuczmera, E. Lork, B. J. Nachtsheim "N-Heterocyclic Iod(az)olium Salts – Potent Halogen-Bond Donors in Organocatalysis" Chem. Eur. J.  2021 DOI: 10.1002/chem.202101961, also published: ChemRxvi  2021 Preprint https://doi.org/10.26434/chemrxiv.14567472.v1

60A.H. Abazid,  T.-N. Hollwedel, B. J. Nachtsheim "Stereoselective Oxidative Cyclization of N-Allyl Benzamides to Oxaz(ol)ines" Org. Lett. 2021DOI:10.1021/acs.orglett.1c01607
59

L.D. Caspers, J. Spils, M. Damrath, E. Lork, B.J. Nachtsheim "One-Pot Synthesis and Conformational Analysis of Six-Membered Cyclic Iodonium Salts"
J. Org. Chem. 2020, 85, 9161–9178,  DOI:10.1021/acs.joc.0c01125

58D. Göbel; P. Rusch; D. Duvinage; N.C. Bigall B. J.  Nachtsheim "Emission color-tunable oxazol(in)yl-substituted excited-state intramolecular proton transfer (ESIPT)-based luminophores"
 Chem. Commun. 2020, 56, 15430-15433. DOI:10.1039/DOCC05780K
57A. Boelke; T. J. Kuczmera; L. D. Caspers; E. Lork; B. J.  Nachtsheim "Iodolopyrazolium Salts: Synthesis, Derivatizations, and Applications"
 Org. Lett. 2020, 22, 7261-7266.  DOI: 10.1021/acs.orglett.0c02593
56D. Göbel; M. Friedrich; E. Lork; B. J.  Nachtsheim "Clickable azide-functionalized bromoarylaldehydes – synthesis and photophysical characterization"
 Beilstein J. Org. Chem. 2020, 16, 1683–1692. Doi:10.3762/bjoc.16.139
55A. Abazid, N. Clamor, B. J. Nachtsheim  "An Enantioconvergent Benzylic Hydroxylation Using a Chiral Aryl Iodide in a Dual Activation Mode"  ACS Catal. 2020, 10, 8042–8048. Doi.org/10.1021/acscatal.0c02321 also published: ChemRxvi 2020 Preprint DOI.org/10.26434/chemrxiv.12103140.v1
54B. J. Nachtsheim  "Mild map to quinone methides"  Nat. Chem. 2020, 12, 326–328.  Doi.org/10.1038/s41557-020-0443-2
53D. Göbel, D. Duvinage, T. Stauch, B. J. Nachtsheim "Nitrile-Substituted 2-(Oxazolinyl)-Phenols: Minimalistic Excited-State Intramolecular Proton Transfer (ESIPT)-Based Fluorophores" J. Mater. Chem. C 2020, 8, 9213 - 9225.  DOI.org/10.1039/D0TC00776E also published: ChemRxiv.2020, Prepint: DOI.org/10.26434/chemrxiv.11786196.v1
52

 A. Boelke, B. J. Nachtsheim "Evolution of N-​Heterocycle-​Substituted Iodoarenes (NHIAs) to Efficient Organocatalysts in Iodine(I​/III)​-​Mediated Oxidative Transformations" Adv. Synth. Catal. 2020, 362, 184 - 191. DOI:10.1002/adsc.201901356

51

A. H. Abazid, B. J. Nachtsheim "A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidations", Angew. Chem. Int. Ed., 2020, 59, 1479-1484. DOI: 10.1002/anie.201912023;  also published: ChemRxiv., 2019, Preprint. DOI.org/10.26434/chemrxiv.9747674.v1.

50

A. Kleinsmann, B. Nachtsheim, "A Minimalistic Hydrolase Based on Co-Assembled Cyclic Dipeptides", Org. Biomol. Chem., 2020, 18, 102 DOI: 10.1039/c9ob02198a; also published: ChemRxiv., 2019, Preprint  DOI.org/10.26434/chemrxiv.9919325.v1

49

A. Boelke, Y. A. Vlasenko, M. Yusubov, B. J. Nachtsheim , P. Postnikov "Thermal Stability of N-Heterocycle-Stabilized Iodanes", J. Org. Chem. 2019, 15, 2311-2318. DOI:10.3762/bjoc.15.223 also published: ChemRxiv., 2019, Preprint. doi.org/10.26434/chemrxiv.8964848.v1

48

D. Göbel,N. Clamor, E. Lork, B. J. Nachtsheim "Aerobic C(sp2)–H Hydroxylations of 2-Aryloxazolines: Fast Access to Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores", Org. Lett. 2019, 21, 5373.   DOI:10.1021/acs.orglett.9b01350.

47

A. Boelke, E. Lork, B. J. Nachtsheim "N-Heterocycle-stabilized Iodanes – From Structure to Reactivity", Chem.Eur. J. 2018, 70, 18653. DOI 10.1002/chem.201804957.

46

A. Boelke, P. Finkbeiner, B. J. Nachtsheim "Atom-economical group-transfer reactions with hypervalent iodine compounds", Beilstein J. Org. Chem. 2018, 14, 1263. DOI:10.3762/bjoc.14.108

45

D. Göbel, N. Clamor, B.J. Nachtsheim "Regioselective ortho-functionalization of bromofluorenecarbaldehydes using TMPMgCl·LiCl", Org. Biomol. Chem. 2018,16, 4071. DOI: 10.1039/C8OB01072B

44

L. D. Caspers, B. J. Nachtsheim "Directing‐Group‐mediated C−H‐Alkynylations" , Chem. Asian J. 2018, 13, 1231. DOI: 10.1002/asia.201800102

43

A. Boelke, L. D. Caspers, B. J. Nachtsheim "NH2-Directed C–H Alkenylation of 2-Vinylanilines with Vinylbenziodoxolones" Org. Lett. 2017, 19, 5344. DOI: 10.1021/acs.orglett.7b02630

42

N. M. Weckenmann, C. Maichle-Moessmer, B. J. Nachtsheim "Template-assisted photodimerization of N-unprotected uracil derivatives - Selective formation of the cis - syn photodimer" Chem. Commun. 2017, 53, 9610.  DOI:10.1039/C7CC05353C

41

C. Hempel, C. Maichle-Mössmer, Miquel A. Pericàs,B. J. Nachtsheim "Modular Synthesis of Triazole-based Chiral Iodoarenes for Enantioselective Spirocyclizations"  Adv. Synth. Catal. 2017359, 2931.  DOI: 10.1002/adsc.2017

40

 L. D. Caspers, P. Finkbeiner, B. J. Nachtsheim "Direct Electrophilic C-H Alkynylation of Unprotected 2-Vinylanilines" Chem. Eur. J. 2017, 23, 2748. DOI: 10.1002/chem.201606026.

39

P. Finkenbeiner, B. J. Nachtsheim "Umpolung von Iminen" Nachrichten aus der Chemie 2015, 63, 1089.

38C. Hempel, B. J. Nachtsheim "Naturstoffsynthese: Sequenzielle C-H-Funktionalisierung" Nachrichten aus der Chemie 2015, 63, 907.
37B. J. Nachtsheim " Synthesen in Kavitäten"  Nachrichten aus der Chemie 2015, 63, 783.
36

C. Hempel, B. J. Nachtsheim "Ohne Umwege - direkte Aminierung von Aliphaten" Nachrichten aus der Chemie 201563, 544.

35P. Finkbeiner, U. Klöckner, B. J. Nachtsheim "OH-Directed Alkynylation of 2-Vinylhenols with Ethynyl Benziodoxolones - A Fast Access to Terminal 1,3-Enynes" Angew. Chem. Int. Ed.  201554, 4949. DOI: 10.1002/anie.201412148.
34W. Xu, B. J. Nachtsheim "TBAI-Catalyzed Oxidative Cross-Coupling of Phenols and 2-Aminoacetophenones" Org. Lett. 2015, 17, 1585. DOI: 10.1021/acs.orglett.5b00466.
33S. Riedmüller, B. J. Nachtsheim "Metal-Free N-Arylation of Indolines with Diaryliodonium Salts" Synlett 201526, 651. DOI: 10.1055/s-0034-1379885.
32B. J. Nachtsheim "E statt Z" Nachrichten aus der Chemie 201563, 36. DOI: 10.1002/nadch.201590007.
31U. Kloeckner, B. J. Nachtsheim "Mild Hypervalent Iodine Mediated Nitration of N-Aryl Sulfonamides" Chem. Commun. 201450, 10485. DOI: 10.1039/C4CC04738A
30B. J. Nachtsheim "Creating Antioxidants by Oxidation Catalysis" Science 2014345, 270, PerspectiveDOI: 10.1126/science.1257347
29A. J. Kleinsmann, N. M. Weckenmann, B. J. Nachtsheim "Phosphate-Triggered Self-Assembly of N-[(Uracil-5-yl)mezthyl]urea: A minimalistic Urea-Derived Hydrogelator" Chem.Eur. J. 201420, 9753. DOI: 10.1002/chem.201402916
28P. Finkbeiner, N. M. Weckenmann, B. J. Nachtsheim "Alkynyliodonium Salt Mediated Alkynylation of Azlactones: Fast Access to Cα-Tetrasubstituted α-Amino Acid Derivatives" Org. Lett. 2014, 16, 1326. DOI: 10.1021/ol500053c.
27S. Riedmüller, O. Kaufhold, H. Spreitzer, B. J. Nachtsheim "Synthesis of Sterically Congested Triarylamines by Palladium-Catalyzed Amination" Eur. J. Org. Chem. 2014, 1391. DOI: 10.1002/ejoc.201400046Highly Accessed
26C. Hempel, B. J. Nachtsheim "Iodine(III)-promoted synthesis of oxazoles through oxidative cyclization of N-styrylbenzamides" Synlett 201324, 2119. DOI: 10.1055/s-0033-1339491.
25A. J. Kleinsmann, B. J. Nachtsheim "Phenylalanine-containing cyclic dipeptides - The lowest molecular weight hydrogelators based on proteinogenic amino acids" Chem. Commun. 201349, 7818. DOI: 10.1039/c3cc44110E.
24S. Riedmüller, B. J. Nachtsheim "Palladium-catalyzed synthesis of N-arylated carbazoles using anilines and cyclic diaryliodonium salts" Beilstein J. Org. Chem. 20139, 1202. DOI: 10.3762/bjoc.9.136.
23W. Xu, U. Klöckner, B. J. Nachtsheim " Direct Synthesis of 2,5-Disubstituted Oxazoles through an Iodine-catalyzed Decarboxylative Domino Reaction" J. Org. Chem. 201378, 6065. DOI: 10.1021/jo400753n.
22P. Finkbeiner, B. J. Nachtsheim "Iodine in Modern Oxidation Catalysis" Synthesis 201345, 979. DOI: 10.1055/s-0032-1318330.
21U. Kloeckner, P. Finkbeiner, B. J. Nachtsheim "Iodide-Catalyzed Halocyclization/Cycloaddition/Elimination Cascade Reaction" J. Org. Chem. 201378, 2751. DOI: 10.1021/jo302676g
20C. Hempel, N. M. Weckenmann, C- Maischle-Moessmer, B. J. Nachtsheim "A hypervalent iodine-mediated spirocyclization of 2-(4-hydroxybenzamido) acrylates – Unexpected formation of δ-spirolactones" Org. Biomol. Chem. 201210, 9325. DOI: 10.1039/C2OB26815A - HOT PAPER
19M. Rueping, B. J. Nachtsheim "Bismuth Salts in Catalytic Alkylation Reactions" in Bismuth Mediated Organic Reactions, Topics  in Current Chemistry 2012311, 115. DOI: 10.1007/128_2011_191.
18U. Kloeckner, N. M. Weckenmann, B. J. Nachtsheim " A Metal-Free Oxidative Amination of Benzoxazoles with Primary Amines and Ammonia" Synlett 201297DOI: 10.1055/s-0031-1289902
17T. Froehr, C. P. Sindlinger, U. Kloeckner, P. Finkbeiner, B. J. Nachtsheim "A Metal-Free Amination of Benzoxazoles - The First Iodide-Catalyzed Oxidative Amination of Heteroarenes" Org. Lett. 201113, 3754. Among the Top 10 most cited artciles published in Organic Letters in 2011DOI:10.1021/ol201439t
16M. Rueping, B. J. Nachtsheim, W. Ieawsuwan, I. Atodiresei "Modulating the Acidity", Angew. Chem. Int. Ed. 201150, 6706. DOI:10.1002/anie.201100169
15M. Rueping, B. J. Nachtsheim, R. M. Koenigs, W. Ieawsuwan, "Synthesis and Structural Aspects of N-Triflylphosphoramides and their Calcium Salts - Highly Acidic and Effective Brønsted Acids" Chem. Eur. J. 201016, 13116. DOI: 10.1002/chem.201001438
14M. Rueping, B. J. Nachtsheim, E. Sugiono "Bi(OTF)3-catalyzed Benzylations of 4-Hydroxycoumarin - Efficient Synthesis of Warfarin Derivatives and Analogues" Synlett 2010, 1549. DOI: 10.1055/s-0029-1219936
13M. Rueping, B. J. Nachtsheim, "Asymmetric Brønsted Acid Catalyzed Nucleophilic Addition to in situ Generated Chiral N-Acyliminium Ions", Synlett 2010, 119. The most cited communication published in Synlett 2010DOI: 10.1055/s-0029-1218539
12M. Rueping, B. J. Nachtsheim "A Review of New Developments in the Friedel-Crafts Alkylation - From Green Chemistry to Asymmetric Catalysis" Beilstein J. Org. Chem. 20106, No. 6. The most cited article ever published in BJOCDOI:  10.3762/bjoc.6.6
11M. Rueping, B. J. Nachtsheim, S. A. Moreth, "Asymmetric Bronsted Acid Catalysis: Enantioselective Nucleophilic Substitutions and 1,4-Additions" Angew. Chem. Int. Ed. 200847, 593. Highlighted in Synfacts (2008, 311)DOI: 10.1002/anie.200703668
10M. Rueping, W. Ieawsuwan, A. P. Antonchick, B. J. Nachtsheim "Chiral Bronsted Acids in the Catalytic Asymmetric Nazarov Cyclization - The First Enantioselective Organocatalytic Electrocyclic Reaction" Angew. Chem. Int. Ed. 200746, 2097. Highlighted in Science (2007, 315, 1055)DOI: 10.1002/anie.200604809
9M. Rueping, B. J. Nachtsheim, A. Kuenkel "An Efficient Metal-Catalyzed Hydroalkylation" Synlett 2007, 1391. DOI: 10.1055/s-2007-980363
8B. J. Nachtsheim, M. Bolte "Pseudosymmetric (E)-methyl 2-oxo-4-phenylbut-3-enoate" Acta Cryst.  2007E63, 2947. DOI: 10.1107/S1600536807024142
7M. Rueping, B. J. Nachtsheim, A. Kuenkel "Efficient Metal-Catalyzed Direct Benzylation and Allylic Alkylation of 2,4-Pentanediones" Org. Lett. 20079, 825. Among the most cited articles 2007DOI: 10.1021/ol063048b.
6M. Rueping, B. J. Nachtsheim, T. Scheidt "Efficient Metal-Catalyzed Hydroarylation of Styrenes" Org. Lett. 20068, 3717. DOI: 10.1021/ol0612962
5M. Rueping, B. J. Nachtsheim, W. Ieawsuwan "An Effective Bismuth-Catalyzed Benzylation of Arenes and Heteroarenes" Adv. Synth. Catal. 2006, 348, 1033. DOI:10.1002/adsc.200606068 Among the most cited articles 2006/2007.

Patents and other Publications

6A. Klemmer, P. Schmiedel, F. Yapici, B. Nachtsheim, D. Göbel; Henkel AG & CO.KGAA, Detergentcompositionhaving flow limit,, WO 2019154613 A1, 2019.
5A. Klemmer, P. Schmiedel, F. Yapici, B. Nachtsheim, D. Göbel; Henkel AG & CO.KGAA, Viscoelastic, solid surfactant composition, WO 2019154612 A1, 2019.
4Ratiopharm GmbH, M. U. Schmidt, J. Bruening, E. Alig, M. Bolte, B. Nachtsheim, Essigsäure Solvate von Risedronat, Polymorph hiervon, deren Herstellung und Verwendung sowie pharmazeutische Zusammensetzung, enthaltend diese, 2009, DE102007030370.1., 1549.
3M. Rueping, B. J. Nachtsheim, “Von der Natur lernen - Enzyme als Vorbild für die moderne Katalysatorforschung.”, Forschung Frankfurt20071, 43.
2M. Rueping, B. J. Nachtsheim, “Enzyme als Vorbild für die Katalysatorforschung.”, ChemiePlus20079, 2.
1S. Nozinovic, B. J. Nachtsheim, S. Scheuermann, J. Schnorr, R. Silvers, M. Wagner, H. Schwalbe, „Learning problem-solving thinking in group work.“, Nachrichten aus der Chemie200553, 978.