Reaction dynamics of metal/oxide catalysts: Methanol oxidation at vanadium oxide films on Rh(111) from UHV to 10(-2) mbar
von Boehn, Christopher Penschke, Xiaoke Li, Joachim Paier, Joachim Sauer, Jon-Olaf Krisponeit, Jan Ingo Flege, Jens Falta, Helder Marchetto, Torsten Franz, Gerhard Lilienkamp, Ronald Imbihl Journal of Catalysis [...] ike” oscillatory expansion and contraction that the islands undergo under stationary conditions. Using density functional theory, the 2D-phase diagram of VO x on Rh(1 1 1) has been computed. The oscillatory