Al(OCArF3)3 – a thermally stable Lewis superacid
Lorka, J. Beckmann Journal: Chemical Science (2018), 9, 8178-8183. http://dx.doi.org/10.1039/C8SC02981D The adduct free Lewis superacid Al(OCAr F 3 ) 3 was obtained by the reaction of Ar F 3 COH with [...] reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCAr F 3 )·D (D = MeCN, THF, Et 2 O, pyridine, OPEt 3 ), the fluoride complexes [Q][FAl(OCAr F ) 3 ] (Q + = Cs +